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Thermal transport in organic/inorganic composites

Bin LIU, Lan DONG, Qing XI, Xiangfan XU, Jun ZHOU, Baowen LI

《能源前沿（英文）》 2018年 第12卷 第1期   页码 72-86 doi: 10.1007/s11708-018-0526-6

摘要： Composite materials, which consist of organic and inorganic components, are widely used in various fields because of their excellent mechanical properties, resistance to corrosion, low-cost fabrication, etc. Thermal properties of organic/inorganic composites play a crucial role in some applications such as thermal interface materials for micro-electronic packaging, nano-porous materials for sensor development, thermal insulators for aerospace, and high-performance thermoelectric materials for power generation and refrigeration. In the past few years, many studies have been conducted to reveal the physical mechanism of thermal transport in organic/inorganic composite materials in order to stimulate their practical applications. In this paper, the theoretical and experimental progresses in this field are reviewed. Besides, main factors affecting the thermal conductivity of organic/inorganic composites are discussed, including the intrinsic properties of organic matrix and inorganic fillers, topological structure of composites, loading volume fraction, and the interfacial thermal resistance between fillers and organic matrix.

关键词： thermal conductivity     organic/inorganic composites     effective medium theory     thermal percolation theory     interfacial thermal resistance    

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Organic and inorganic phosphorus uptake by bacteria in a plug-flow microcosm

Jinbo ZHAO, Xuehua LIU

《环境科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 173-184 doi: 10.1007/s11783-013-0494-3

摘要： Phosphorus (P) is a vital nutrient for sustaining natural water productivity. Both particulate and dissolved forms of organic and inorganic P are potentially important sources of bioavailable P for primary and secondary producers. A microcosm system to imitate the bacterial community in Plym river sediment and pore water is described and bacterial uptake rates for inorganic and organic phosphorus are presented in this paper. The aim of this study was to investigate the uptake of two organic phosphorus compounds (phytic acid and D-glucose-6-phosphate) by freshwater bacteria. The bioreactors comprise glass columns packed with two types of small glass beads on which bacterial biofilm can develop. The glass beads with different porosity were introduced to simulate River SPM. The selected P compounds spiked into the inflow of the microcosm, and measured the step change of P concentration in the outflow to investigate the behavior of bacterial uptake of nutrients. The results showed that organic phosphorus was converted into inorganic phosphorus but the conversion rate depended on the type of phosphorus species. One experiment suggested that phytic acid (refractory) could displace phosphate from the biofilm surface; the other experiment showed that D-glucose-6-phosphate (labile) could be hydrolysed and utilized easily by the bacteria. The results also suggested that bacteria might break down the C-P bonds to utilize the carbon. Further experiments should investigate the effect of varying the C:N:P ratio in the microcosm system to determine which nutrient limits bacteria uptake.

关键词： organic phosphorus     bacteria     uptake    

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Immobilization of laccase on organic–inorganic nanocomposites and its application in the removal of phenolic

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 867-879 doi: 10.1007/s11705-022-2277-5

摘要： Polydopamine-functionalized nanosilica was synthesized using an inexpensive and easily obtainable raw material, mild reaction conditions, and simple operation. Subsequently, a flexible spacer arm was introduced by using dialdehyde starch as a cross-linking agent to bind with laccase. A high loading amount (77.8 mg∙g‒1) and activity retention (75.5%) could be achieved under the optimum immobilization conditions. Thermodynamic parameters showed that the immobilized laccase had a lower thermal deactivation rate constant and longer half-life. The enhancement of thermodynamic parameters indicated that the immobilized laccase had better thermal stability than free laccase. The residual activity of immobilized laccase remained at about 50.0% after 30 days, which was 4.0 times that of free laccase. Immobilized laccase demonstrated excellent removal of phenolic pollutants (2,4-dichlorophenol, bisphenol A, phenol, and 4-chlorophenol) and perfect reusability with 70% removal efficiency retention for 2,4-dichlorophenol after seven cycles. These results suggested that immobilized laccase possessed great reusability, improved thermal stability, and excellent storage stability. Organic–inorganic nanomaterials have a good application prospect for laccase immobilization, and the immobilized laccase of this work may provide a practical application for the removal of phenolic pollutants.

关键词： polydopamine     pollutant removal     thermodynamic     phenolic pollutants     immobilized laccase    

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Nanosilver anchored alginate/poly(acrylic acid/acrylamide) double-network hydrogel composites for efficientcatalytic degradation of organic dyes

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 893-905 doi: 10.1007/s11705-022-2290-8

摘要： A novel alginate/poly(acrylic acid/acrylamide) double-network hydrogel composite with silver nanoparticles was successfully fabricated using the sol–gel method. The presence of carboxyl and amide groups in the network structure provided abundant active sites for complexing silver ions, facilitating the in situ reduction and confinement of silver nanoparticles. In batch experiments, the optimal silver loading was 20%, and 5 mmol·L–1 of p-nitrophenol was completely degraded in 113 s with a rate constant value of 4.057 × 10−2 s–1. In the tap water system and simulated seawater system, the degradation time of p-nitrophenol at the same concentration was 261 and 276 s, respectively, with a conversion rate above 99%. In the fixed-bed experiment, the conversion rate remained above 74% after 3 h at a flowing rate of 7 mL·min–1. After 8 cycling tests, the conversion rate remained at 98.7%. Moreover, the catalyst exhibited outstanding performance in the degradation experiment of four typical organic dyes.

关键词： double-network hydrogel     dye degradation     silver nanoparticles     alginate    

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Sustainable wood-based nanotechnologies for photocatalytic degradation of organic contaminants in aquatic

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1346-6

摘要：

•Wood and its reassemblies are ideal substrates to develop novel photocatalysts.

关键词： Wood     Nanocatalysts     Photodegradation     Organic contaminants     Composites    

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Phenolic rigid organic filler/isotactic polypropylene composites. III. Impact resistance property

Heming LIN, Dongming QI, Jian HAN, Zhiqi CAI, Minghua WU

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 176-181 doi: 10.1007/s11705-009-0203-8

摘要： A novel phenolic rigid organic filler (KT) was used to modify isotactic polypropylene (iPP). The influence of KT particles on the impact resistance property of PP/KT specimens (with similar interparticles distance, 1.8 μm) was studied by notched izod impact tests. It was found that the brittle-ductile transition (BDT) of the PP/KT microcomposites took place at the filler content of about 4%, and the impact strength attains the maximum at 5% (with filler particles size of 1.5 μm), which is about 2.5 times that of unfilled iPP specimens. The impact fracture morphology was investigated by scanning electron microscopy (SEM). For the PP/KT specimens and the high-density polyethylene/KT (HDPE/KT) specimens in ductile fracture mode, many microfibers could be found on the whole impact fracture surface. It was the filler particles that induced the plastic deformation of interparticles ligament and hence improved the capability of iPP matrix on absorbing impact energy dramatically. The determinants on the BDT were further discussed on the basis of stress concentration and debonding resistance. It can be concluded that aside from the interparticle distance, the filler particles size also plays an important role in semicrystalline polymer toughening.

关键词： rigid organic filler     polypropylene     impact resistance    

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Phenolic rigid organic filler/isotactic polypropylene composites. II. Tensile properties

QI Dongming, SHAO Jianzhong, WU Minghua, NITTA Kohhei

《化学科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 396-401 doi: 10.1007/s11705-008-0077-1

摘要： A novel phenolic rigid organic filler (KT) was used to modify isotactic polypropylene (iPP). The influence of KT particles on the tensile properties of PP/KT microcomposites was studied by uniaxial tensile test and the morphological structures of the stretched specimens were observed by scanning electron microscopy (SEM) and polarized optical microscopy (POM). We found that the Young’s modulus of PP/KT specimens increased with filler content, while the yield and break of the specimens are related to the filler particles size. The yield stress, the breaking stress and the ultimate elongation of PP/KT specimens were close to those of unfilled iPP specimens when the maximal filler particles size is less than a critical value, which is 7 ?m at a crosshead speed of 10 mm/min and 3 ?m at 200 mm/min, close to that of glass bead but far more than those of other rigid inorganic filler particles. The interfacial interaction was further estimated from yield stress, indicating that KT particles have a moderate interfacial interaction with iPP matrix. Thus, the incorporation of small KT particles can reinforce iPP matrix and simultaneously cause few detrimental effects on the other excellent tensile properties of iPP matrix, due to their organic nature, higher specific area, solid true-spherical shape and the homogenous dispersion of the ROF particles in microcomposites.

关键词： maximal     uniaxial tensile     unfilled     excellent tensile     influence    

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Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

《能源前沿（英文）》 2019年 第13卷 第1期   页码 163-171 doi: 10.1007/s11708-018-0554-2

摘要： This paper focuses on the superiority of organic-inorganic hybrid ion-gel electrolytes for lithium-ion batteries (LiBs) over commercial electrolytes, such as 1 M LiPF in 1:1 ethylene carbonate (EC): dimethyl carbonate (DMC) {1 M LiPF -EC: DMC}, in terms of their flame susceptibility. These ion-gel electrolytes possess ionic liquid monomers, which are confined within the borosilicate or silicate matrices that are ideal for non-flammability. Naked flame tests confirm that the organic-inorganic hybrid electrolytes are less susceptible to flames, and these electrolytes do not suffer from a major loss in terms of weight. In addition, the hybrids are self-extinguishable. Therefore, these hybrids are only oxidized when subjected to a flame unlike other commercial electrolytes used in lithium-ion batteries. Supplementary analyses using differential scanning calorimetric studies reveal that the hybrids are glassy until the temperature reaches more than 100°C. The current results are consistent with previously published data on the organic-inorganic hybrids.

关键词： inorganic polymeric borosilicate network     organic-inorganic hybrids     self-extinguishability     nonflammability     lithium batteries     flame-retardants    

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Phenolic rigid organic filler/isotactic polypropylene composites. I. Preparation

QI Dongming, YANG Lei, WU Minghua, LIN Heming, NITTA Kohhei

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 236-241 doi: 10.1007/s11705-008-0034-z

摘要： A novel phenolic rigid organic filler (KT) was melt-mixed with an isotactic polypropylene (iPP) to prepare a series of PP/KT composites, with or without maleic anhydride grafted polypropylene (MAPP) as compatilizer. The evolution of filler morphology during melt-mixing and melt-pressure processes was monitored by scanning electron microscope (SEM) and polarized optical microscope (POM). The influences of shear force, pressure time, filler content and MAPP concentration on the final filler dispersion were studied. We found that this rigid organic filler readily melted and dispersed homogenously into the iPP matrix through a fission-fusion process during the melt-mixing process. Thus a balanced dispersion, which was closely related to shear force and MAPP concentration, can be achieved. During the melt-pressure process, parts of the filler particles combined gradually through a coalescence process. However, the incorporation of MAPP can effectively inhibit the tendency to coalesce and refine the filler particles sizes into nanoscale. Thus, a series of PP/KT composites with controllable filler particles size and narrow size distribution can be obtained just by adjusting process conditions and MAPP concentration. In addition, due to the in-situ formation mechanism, the filler phase possessed a typical solid true-spherical shape.

关键词： morphology     concentration     tendency     controllable     addition    

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Simultaneous sorption of aqueous phenanthrene and phosphate onto bentonites modified with AlCl3 and CTMAB

ZHU Runliang, ZHU Lizhong, ZHU Jianxi

《环境科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 79-82 doi: 10.1007/s11783-007-0015-3

摘要： The purpose of this work is to synthesize a new type of bentonite sorbent that can simultaneously remove both organic compounds and phosphate from water. Inorganic-organic bentonites (Al-CTMAB-Bent) were synthesized by modifying bentonites with both AlCl3 and cetyltrimethyl ammonium bromide (CTMAB). Simultaneous sorption of aqueous phenanthrene and phosphate onto Al-CTMAB-Bent was examined. Removal rates of phenanthrene and phosphate from water reached 96.3% and 90.2%, respectively, at their respective initial concentrations of 1 mg/L and 5 mg/L and the added amount of Al-CTMAB-Bent was 1.25 g/L. The residual turbidity of the Al-CTMAB-Bent suspension decreased 81.4% compared to that of organobentonite suspension after a 1 h settling time. Thus, inorganic-organic bentonite can be used to treat wastewater containing both organic pollutants and phosphate.

关键词： phenanthrene     settling     respective     residual turbidity     Inorganic-organic    

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含高浓度无机颗粒的有机废液分离及回用技术 Article

汪华林, 付鹏波, 李剑平, 黄渊, 赵颖, 姜来, 方向晨, 杨涛, 黄朝晖, 黄诚

《工程（英文）》 2018年 第4卷 第3期   页码 406-415 doi: 10.1016/j.eng.2018.05.014

摘要：

有机废液的无害化、资源化处理是环境工程的前沿之一，随着化学品需求不断增加，石油、煤和天然气转化中排放的含高浓度无机污染物的有机废液问题更趋严重。本文通过同步高速摄像技术发现了三维旋转湍流场中颗粒物高速自转和翻转现象，自转速度高达2000~6000 rad·s-1，利用这一现象发明了颗粒物孔隙中有机物旋流自转脱除方法，开发了废液中有机污染物旋流自转回收、无机颗粒物气流加速度分级回用的工艺流程，并成功应用于中国石化第一套自主研发的沸腾床渣油加氢工程示范装置中。该技术与美国T-STAR含废催化剂的有机废液固定床气提技术相比，同温度下催化剂颗粒脱液效率最高可提高44.9个百分点，实现95%脱液效率的处理时间从1956.5 s降低到8.4 s，并实现了外排催化剂颗粒按活性分级进行回用。提出了200万吨/年沸腾床渣油加氢装置的外排有机废液控制及无机颗粒回收利用技术方案，预期可回收柴油3100吨/年，高活性催化剂颗粒647吨/年，降低装置新鲜催化剂消耗量518吨/年，直接经济效益3728万元/年，具有显著的经济、社会和环境效益。

关键词： 有机废液     无机颗粒     旋流脱液     颗粒自转     气流加速度分选    

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Formation of secondary inorganic aerosol in a frigid urban atmosphere

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1452-0

摘要：

•Harbin showed relatively high threshold RH (80%) for apparent increase of SOR.

关键词： Haze     Sulfate     Nitrate     Heterogeneous chemistry     Biomass burning     Northeast China    

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Spectrokinetics study of probable effects of diverse inorganic ions on bleaching of dye

Rafia AZMAT, Masooda QADRI, Fahim UDDIN

《化学科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 131-138 doi: 10.1007/s11705-010-0556-z

摘要： Toluidine blue (TB) is an important anticoagulant metachromasia molecule showing a pronounced variation in the visible spectrum due to the aggregation phenomenon and electrostatic interaction with the charged synthetic and biologic polymers. The current study describes the interactive role of diverse inorganic material ions on the bleaching of toluidine blue (tolonium chloride) (TB ) with urea in acidic and basic media using the spectrophotometric technique. The spectra of TB and urea with different cations and anions were monitored and their characteristic features are presented here. The negative effect of added cations on reduction may be the result of altered electron pathways which led to suppression of the reduction/bleaching of TB, while a slight decrease in dye reduction by added anions may be due to the scavenging of the OH* radical. It has been observed in the case of Co that in addition to the electron-transfer reaction, other processes like layer and precipitate formation also appear to be taking place. The dye bleaching process followed pseudo first order kinetics with respect to TB, urea, and H ion, whereas significant decoloration in the presence of urea proved that reductants control the redox reaction. No decoloration in acidic medium with diverse ions was seen compared to alkaline media, showing that water pH played an important role in the bleaching of dye. The reduction/bleaching of dye was investigated at different temperatures, and energy parameters were evaluated for a TB -Urea reaction, including the energy of activation ( = 39.60 kJ·mol ), enthalpy of activation (? = 34?kJ·mol ), entropy of activation (? = 146.5 kJ mol ·K ), and free energy of activation (ΔG* = -52.35 kJ·mol ). A mechanism of interaction of diverse ions in dye bleaching and a mechanism of reduction based on the above findings is proposed.

关键词： TB     diverse ions     suppress     decoloration    

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Characteristics of chemical components in PM

Jianwu SHI,Xiang DING,Yue ZHOU,Ran YOU,Lu HUANG,Jiming HAO,Feng XIANG,Jian YANG,Ze SHI,Xinyu HAN,Ping NING

《环境科学与工程前沿（英文）》 2016年 第10卷 第5期 doi: 10.1007/s11783-016-0841-2

摘要： The mass concentrations of PM were studied at a plateau city. Seasonal and spatial variation of chemical components in PM were analyzed. Primary emissions were the main contributors of PM . A sampling campaign including summer, autumn and winter of 2014 and spring of 2015 was accomplished to obtain the characteristic of chemical components in PM at three sites of Kunming, a plateau city in South-west China. Nine kinds of water-soluble inorganic ions (WSI), organic and element carbon (OC and EC) in PM were analyzed by ion chromatography and thermal optical reflectance method, respectively. Results showed that the average concentrations of total WSI, OC and EC were 22.85±10.95 μg·m , 17.83±9.57 μg·m and 5.11±4.29 μg·m , respectively. They totally accounted for 53.0% of PM . Secondary organic and inorganic aerosols (SOA and SIA) were also assessed by the minimum ratio of OC/EC, nitrogen and sulfur oxidation ratios. The annual average concentrations of SOA and SIA totally accounted for 28.3% of the PM concentration. The low proportion suggested the primary emission was the main source of PM in Kunming. However, secondary pollution in the plateau city should also not be ignorable, due to the appropriate temperature and strong solar radiation, which can promote the atmospheric photochemical reactions.

关键词： PM2.5     Plateau city     Organic carbon     Element carbon     Inorganic ions     Secondary components    

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The influence of curing conditions on the mechanical properties and leaching of inorganic polymers made

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 317-327 doi: 10.1007/s11705-017-1622-6

摘要： This study reports on the impact of the curing conditions on the mechanical properties and leaching of inorganic polymer (IP) mortars made from a water quenched fayalitic slag. Three similar IP mortars were produced by mixing together slag, aggregate and activating solution, and cured in three different environments for 28 d: a) at 20 °C and relative humidity (RH) ~ 50% (T20RH50), b) at 20 °C and RH≥90% (T20RH90) and c) at 60 °C and RH ~ 20% (T60RH20). Compressive strength (EN 196-1) varied between 19 MPa (T20RH50) and 31 MPa (T20RH90). This was found to be attributed to the cracks formed upon curing. Geochemical modelling and two leaching tests were performed, the EA NEN 7375 tank test, and the BS EN 12457-1 single batch test. Results show that Cu, Ni, Pb, Zn and As leaching occurred even at high pH, which varied between 10 and 11 in the tank test’s leachates and between 12 and 12.5 in the single batch’s leachates. Leaching values obtained were below the requirements for non-shaped materials of Flemish legislation for As, Cu and Ni in the single batch test.

关键词： inorganic polymer     geochemical leaching modelling     heavy metals     recycling     non-ferrous fayalitic slag     curing    

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标题 作者 时间 类型 操作

Thermal transport in organic/inorganic composites

Bin LIU, Lan DONG, Qing XI, Xiangfan XU, Jun ZHOU, Baowen LI

期刊论文

Organic and inorganic phosphorus uptake by bacteria in a plug-flow microcosm

Jinbo ZHAO, Xuehua LIU

期刊论文

Immobilization of laccase on organic–inorganic nanocomposites and its application in the removal of phenolic

期刊论文

Nanosilver anchored alginate/poly(acrylic acid/acrylamide) double-network hydrogel composites for efficientcatalytic degradation of organic dyes

期刊论文

Sustainable wood-based nanotechnologies for photocatalytic degradation of organic contaminants in aquatic

期刊论文

Phenolic rigid organic filler/isotactic polypropylene composites. III. Impact resistance property

Heming LIN, Dongming QI, Jian HAN, Zhiqi CAI, Minghua WU

期刊论文

Phenolic rigid organic filler/isotactic polypropylene composites. II. Tensile properties

QI Dongming, SHAO Jianzhong, WU Minghua, NITTA Kohhei

期刊论文

Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

期刊论文

Phenolic rigid organic filler/isotactic polypropylene composites. I. Preparation

QI Dongming, YANG Lei, WU Minghua, LIN Heming, NITTA Kohhei

期刊论文

Simultaneous sorption of aqueous phenanthrene and phosphate onto bentonites modified with AlCl3 and CTMAB

ZHU Runliang, ZHU Lizhong, ZHU Jianxi

期刊论文

含高浓度无机颗粒的有机废液分离及回用技术

汪华林, 付鹏波, 李剑平, 黄渊, 赵颖, 姜来, 方向晨, 杨涛, 黄朝晖, 黄诚

期刊论文

Formation of secondary inorganic aerosol in a frigid urban atmosphere

期刊论文

Spectrokinetics study of probable effects of diverse inorganic ions on bleaching of dye

Rafia AZMAT, Masooda QADRI, Fahim UDDIN

期刊论文

Characteristics of chemical components in PM

Jianwu SHI,Xiang DING,Yue ZHOU,Ran YOU,Lu HUANG,Jiming HAO,Feng XIANG,Jian YANG,Ze SHI,Xinyu HAN,Ping NING

期刊论文

The influence of curing conditions on the mechanical properties and leaching of inorganic polymers made

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

期刊论文